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The microstructure of martensite and its implications for the shape- memory effect. (English) Zbl 0813.73056

Kinderlehrer, David (ed.) et al., Microstructure and phase transition. Based on the proceedings of a workshop which was an integral part of the 1990-91 IMA program on phase transitions and free boundaries. New York, NY: Springer-Verlag. IMA Vol. Math. Appl. 54, 1-25 (1993).
This work describes a macroscopic approach based on continuum mechanics to martensitic phase transformations in elastic crystalline solids. Such transformations are sudden phase transitions from austenite phase with higher symmetries to martensite phase with lower symmetries. A phase transition manifests itself as jumps in homogeneous deformation gradients across a planar surface of discontinuity. Deformation gradients consist only of pure stretch tensor, and their jumps are governed by well-known Hadamard conditions. These jump conditions, coupled with the minimization of total strain energy, are employed to study the formation of wedge-like microstructures from martensite to austenite which play an important role in the behaviour of shape-memory alloys and in the phenomenon of self- accomodation, in which martensite arranges itself in such a microstructure that there is no change in its macroscopic shape. For various crystal classes, the necessary and sufficient conditions for such formations are obtained and are associated with lattice parameters. Theoretical results are compared with available experimental data, and a rather good agreement is observed.
For the entire collection see [Zbl 0787.00039].

MSC:

74A60 Micromechanical theories
74M25 Micromechanics of solids
82B26 Phase transitions (general) in equilibrium statistical mechanics
74E10 Anisotropy in solid mechanics
74A15 Thermodynamics in solid mechanics
82D25 Statistical mechanics of crystals