Summary: By extending the semi-classical quantum tunneling method, the tunneling radiation of the massive charged particle from a charged Reissner-Nordström-NUT black hole was investigated. Difference from the uncharged mass-less particle, the geodesics of the charged massive particle tunneling from the black hole is not light-like, but determined by the phase velocity. The result shows that the tunneling rate depends on the emitted particle’s energy, NUT parameter and electric charge, and takes the same functional form as uncharged particle. It also proves that the exact emission spectrum is not strictly pure thermal, but is consistent with the underlying unitary theory.